Double Pseudo-Polymeric Gold(III)-Mercury(II) Complexes [Au(S2CNR2)2]nX [R2 = (CH2)6, (CH2)4O] Containing ([HgCl3]−)n, [HgCl4]2− and [Hg2Cl6]2− Anions: Chemisorption Synthesis, Principles of Supramolecular Self-Assembly, and Thermal Behavior
- 作者: Loseva O.1, Rodina T.1, Ivanov A.1
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隶属关系:
- Institute of Geology and Nature Management
- 期: 卷 89, 编号 11 (2019)
- 页面: 2273-2284
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223169
- DOI: https://doi.org/10.1134/S1070363219110185
- ID: 223169
如何引用文章
详细
Novel pseudo-polymeric complexes of gold(III)-mercury(II) with cyclic alkylene dithiocarbamate ligands: ([Au{S2CN(CH2)6}2][HgCl3])n, ([Au{S2CN(CH2)6}2]2[HgCl4]·H2O)n, and ([Au{S2CN(CH2)4O}2]2[Hg2Cl6])n have been obtained and structurally characterized. The sophisticated supramolecular structure of the obtained compounds is realized due to secondary non-valent Au⋯S interactions and includes mononuclear and binuclear cations and anions as structural units as well as cationic and anionic polymer chains. The thermal behavior of the obtained complexes has been studied by means of simultaneous thermal analysis. The products of thermal transformations of the complexes are reduced elemental gold and HgCl2.
作者简介
O. Loseva
Institute of Geology and Nature Management
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, Blagoveschensk, 675000
T. Rodina
Institute of Geology and Nature Management
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, Blagoveschensk, 675000
A. Ivanov
Institute of Geology and Nature Management
编辑信件的主要联系方式.
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, Blagoveschensk, 675000