Luminescent Complexes of Zn(II) and Cd(II) with Chiral Ligands Containing 1,10-Phenanthroline and Natural Monoterpenoids (+)-3-Carene or (+)-Limonene Fragments
- 作者: Kokina T.1,2, Ustimenko Y.3, Rakhmanova M.1, Sheludyakova L.1,2, Agafontsev A.3, Plyusnin P.1,2, Tkachev A.2,3, Larionov S.1,2
-
隶属关系:
- A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- 期: 卷 89, 编号 1 (2019)
- 页面: 87-95
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222708
- DOI: https://doi.org/10.1134/S107036321901016X
- ID: 222708
如何引用文章
详细
New chiral 1,10-phenanthroline-derived ligands containing fragments of (+)-3-carene (L1) and (+)-limonene (L2) natural monoterpenoids and their complexes Zn(L1,2)Cl2·1.5H2O, Cd(L1,2)Cl2·nH2O, Zn(L1)Br2·2H2O, and Cd(L1)Br2·2H2O were synthesized. According to NMR and IR spectroscopy data, a conclusion was made about the polynuclear structure of the compounds obtained. Luminescent properties of the compounds obtained were investigated. Lifetimes of the excited states and luminescence quantum yields (φf) were determined. For free ligands, blue fluorescence was observed. In the case of Zn(II) and Cd(II) complexes, luminescence appeared in the green region of the spectrum.
关键词
作者简介
T. Kokina
A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
编辑信件的主要联系方式.
Email: kokina@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk
Yu. Ustimenko
N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: kokina@niic.nsc.ru
俄罗斯联邦, Novosibirsk
M. Rakhmanova
A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: kokina@niic.nsc.ru
俄罗斯联邦, Novosibirsk
L. Sheludyakova
A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: kokina@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk
A. Agafontsev
N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: kokina@niic.nsc.ru
俄罗斯联邦, Novosibirsk
P. Plyusnin
A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: kokina@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk
A. Tkachev
Novosibirsk National Research State University; N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: kokina@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk
S. Larionov
A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: kokina@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk