Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior
- 作者: Korneeva E.1, Loseva O.1, Smolentsev A.2,3, Ivanov A.1
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隶属关系:
- Institute of Geology and Nature Management, Far East Branch
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- 期: 卷 88, 编号 8 (2018)
- 页面: 1681-1689
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222371
- DOI: https://doi.org/10.1134/S1070363218080200
- ID: 222371
如何引用文章
详细
New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).
作者简介
E. Korneeva
Institute of Geology and Nature Management, Far East Branch
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, per. Relochnyi 1, Blagoveshchensk, 675000
O. Loseva
Institute of Geology and Nature Management, Far East Branch
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, per. Relochnyi 1, Blagoveshchensk, 675000
A. Smolentsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 1, Novosibirsk, 630090
A. Ivanov
Institute of Geology and Nature Management, Far East Branch
编辑信件的主要联系方式.
Email: alexander.v.ivanov@chemist.com
俄罗斯联邦, per. Relochnyi 1, Blagoveshchensk, 675000