Synthesis and Structure of Tetraphenylphosphonium Carboxylates
- 作者: Sharutin V.1, Sharutina O.1, Rybakova A.1, Gubanova Y.1
-
隶属关系:
- National South Ural Research State University
- 期: 卷 88, 编号 8 (2018)
- 页面: 1629-1634
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222361
- DOI: https://doi.org/10.1134/S1070363218080133
- ID: 222361
如何引用文章
详细
Hydrates of tetraphenylphosphonium carboxylates were synthesized by the reaction of equimolar amounts of pentaphenylphosphorus with 2-methoxybenzoic, 2-nitrobenzoic, and maleic acids in benzene. The product of the pentaphenylphosphorus reaction with tetrafluorophthalic acid (mole ratio 2: 1) is bis- (tetraphenylphosphonium) tetrafluorophthalate hydrate. According to the X-ray analysis data, crystals of tetraphenylphosphonim carboxylates are formed by tetraphenylphosphonim tetrahedral cations and single- or double-charged carboxylate anions. Structural organization of the crystals is determined by C–H···O weak hydrogen bonds formed with the participation of carboxylate groups and water molecules or manifold C–H···F interactions between cations and anions.
作者简介
V. Sharutin
National South Ural Research State University
编辑信件的主要联系方式.
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
National South Ural Research State University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
A. Rybakova
National South Ural Research State University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
Yu. Gubanova
National South Ural Research State University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080