Synthesis of Isomeric Dinitro and Diamino Derivatives of Polycyclic Crown Ethers: Dibenzo-18-crown-6 and Dibenzo-24-crown-8
- 作者: Glushko V.1, Sadovskaya N.1, Blokhina L.1, Zhila M.1, Belus’ S.1, Vashchenkova E.1, Shmelevaa I.1
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隶属关系:
- Institute of Chemical Reagents and High Purity Chemical Substances, “
- 期: 卷 88, 编号 8 (2018)
- 页面: 1595-1600
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222354
- DOI: https://doi.org/10.1134/S1070363218080078
- ID: 222354
如何引用文章
详细
Specific features of the synthesis of polycyclic crown ethers dibenzo-18-crown-6 and dibenzo-24-crown-8 and their dinitro and diamino derivatives have been studied. A mixture of isomers of dibenzocrown ether derivatives was obtained and separated. The spectral and thermal characteristics of the synthesized compounds and the kinetics of synthesis of dibenzo-24-crown-8 by the two-component condensation of pyrocatechol with 1-chloro-2-[2-(2-chloroethoxy)ethoxy]ethane in an alcoholic medium in the presence of a KOH template agent were studied.
作者简介
V. Glushko
Institute of Chemical Reagents and High Purity Chemical Substances, “
编辑信件的主要联系方式.
Email: tetrazoli@yandex.ru
俄罗斯联邦, Bogorodskii val 3, Moscow, 107076
N. Sadovskaya
Institute of Chemical Reagents and High Purity Chemical Substances, “
Email: tetrazoli@yandex.ru
俄罗斯联邦, Bogorodskii val 3, Moscow, 107076
L. Blokhina
Institute of Chemical Reagents and High Purity Chemical Substances, “
Email: tetrazoli@yandex.ru
俄罗斯联邦, Bogorodskii val 3, Moscow, 107076
M. Zhila
Institute of Chemical Reagents and High Purity Chemical Substances, “
Email: tetrazoli@yandex.ru
俄罗斯联邦, Bogorodskii val 3, Moscow, 107076
S. Belus’
Institute of Chemical Reagents and High Purity Chemical Substances, “
Email: tetrazoli@yandex.ru
俄罗斯联邦, Bogorodskii val 3, Moscow, 107076
E. Vashchenkova
Institute of Chemical Reagents and High Purity Chemical Substances, “
Email: tetrazoli@yandex.ru
俄罗斯联邦, Bogorodskii val 3, Moscow, 107076
I. Shmelevaa
Institute of Chemical Reagents and High Purity Chemical Substances, “
Email: tetrazoli@yandex.ru
俄罗斯联邦, Bogorodskii val 3, Moscow, 107076