Synthesis and Characterization of Zn(II) Complexes of 2-(7-Bromo-2-oxo-5-phenyl-2,3-dihydro-1H-1,4-benzodiazepin-1-yl)acetohydrazide and Its Condensation Products with Pyruvic Acid and Isatin
- 作者: Pulya A.1, Seifullina I.1, Skorokhod L.1, Vlasenko V.2, Trigub A.3, Rakipov I.4
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隶属关系:
- Mechnikov Odessa National University
- Research Institute of Physics
- Kurchatov Institute National Research Center
- Odessa National Polytechnic University
- 期: 卷 88, 编号 2 (2018)
- 页面: 271-276
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221998
- DOI: https://doi.org/10.1134/S1070363218020135
- ID: 221998
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详细
The systems ZnCl2–2-(7-bromo-2-oxo-5-phenyl-2,3-dihydro-1H-1,4-benzodiazepin-1-yl)acetohydrazide (Hydr)–propan-2-ol, ZnCl2–Hydr–pyruvic acid (HPv), and Zn(CH3COO)2–Hydr–isatin(HIz)–propan-2-ol were studied. Optimal synthesis conditions were determined, and the complexes [Zn(Hydr)2Cl2], [Zn(HydrHPv)2Cl2], and [Zn(HydrIz)2] were isolated. The complexes were characterized by elemental analysis, thermogravimetry, IR spectroscopy, and mass spectrometry. The electrical conductivities of the complexes were measured. The local environment of the central atom in the coordination entity was determined by X-ray absorption spectroscopy.
作者简介
A. Pulya
Mechnikov Odessa National University
编辑信件的主要联系方式.
Email: lborn@ukr.net
乌克兰, ul. Dvoryanskaya 2, Odessa
I. Seifullina
Mechnikov Odessa National University
Email: lborn@ukr.net
乌克兰, ul. Dvoryanskaya 2, Odessa
L. Skorokhod
Mechnikov Odessa National University
Email: lborn@ukr.net
乌克兰, ul. Dvoryanskaya 2, Odessa
V. Vlasenko
Research Institute of Physics
Email: lborn@ukr.net
俄罗斯联邦, Rostov-on-Don
A. Trigub
Kurchatov Institute National Research Center
Email: lborn@ukr.net
俄罗斯联邦, Moscow
I. Rakipov
Odessa National Polytechnic University
Email: lborn@ukr.net
乌克兰, Odessa