Low-temperature equilibriums in solutions of isocyanide-phosphine complexes of palladium(II) chloride
- 作者: Kinzhalov M.1, Buldakov A.1, Petrov A.1, Mahmudov K.2, Ivanov A.1, Suslonov V.1
-
隶属关系:
- St. Petersburg State University
- Technical University of Lisbon
- 期: 卷 87, 编号 11 (2017)
- 页面: 2605-2611
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221585
- DOI: https://doi.org/10.1134/S1070363217110159
- ID: 221585
如何引用文章
详细
cis-[PdCl2(CNR)(PPh3)] [R = Cy, t-Bu, C(Me)2CH2C(Me)3] have been synthesized via the interaction of [(PPh3)ClPd(μ-Cl)2PdCl(PPh3)] with isocyanide in CH2Cl2 at room temperature with 90–98% yield and characterized by means of mass spectrometry as well as 1H, 13C{1H, 31P}, and 31P{1H} NMR spectroscopy. The complexes structure in the solid phase has been elucidated by means of X-ray diffraction analysis. Dynamic processes in the solutions of the complexes in CDCl3 and CD2Cl2 at temperature of–95 to 60°С have been studied by means of 1H and 31P NMR spectroscopy. It has been found that the studied compounds existed exclusively in the cis-[PdCl2(CNR)(PPh3)] form in the solutions. In the case of cis-[PdCl2(CNCy)(PPh3)] in CH2Cl2, the conformational transitions of the equilibrium forms (the transition of the substituent in the cyclohexyl cycle between the equatorial and axial positions) are slowed down, the equatorial conformer prevailing in the solution (2: 1 at–95°С). Quantum-chemical simulation (DFT) has revealed that the standard Gibbs energy of the conformational transition from the axial form of cis-[PdCl2(CNCy)(PPh3)] into the equatorial one in the CH2Cl2 solution at 178 K equals–2.5 kJ/mol, being in agreement with the experimental data.
作者简介
M. Kinzhalov
St. Petersburg State University
编辑信件的主要联系方式.
Email: m.kinzhalov@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Buldakov
St. Petersburg State University
Email: m.kinzhalov@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Petrov
St. Petersburg State University
Email: m.kinzhalov@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
K. Mahmudov
Technical University of Lisbon
Email: m.kinzhalov@spbu.ru
葡萄牙, Lisbon
A. Ivanov
St. Petersburg State University
Email: m.kinzhalov@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
V. Suslonov
St. Petersburg State University
Email: m.kinzhalov@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034