Synthesis and coordination properties of nitro derivatives of 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin
- 作者: Kuvshinova E.1, Vershinina I.2, Syrbu S.1, Golubchikov O.1
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隶属关系:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- 期: 卷 87, 编号 9 (2017)
- 页面: 2181-2187
- 栏目: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
- URL: https://journals.rcsi.science/1070-3632/article/view/221349
- DOI: https://doi.org/10.1134/S1070363217090444
- ID: 221349
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详细
Methods were developed for the synthesis of nitro derivatives of 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin containing nitro groups at the meso positions of the porphyrin core and at the para positions of the phenyl substituents. The formation kinetics of the zinc, copper, and cobalt complexes of the resultant porphyrins in pyridine and in an acetic acid–benzene (7 : 3) mixed solvent was studied. It was found that the properties of the porphyrin ligands are determined both by the electronic effect of the nitro groups and by the effects of spatial distortion of the porphyrin core.
作者简介
E. Kuvshinova
Ivanovo State University of Chemistry and Technology
编辑信件的主要联系方式.
Email: kuvshinovae@isuct.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000
I. Vershinina
Krestov Institute of Solution Chemistry
Email: kuvshinovae@isuct.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153045
S. Syrbu
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000
O. Golubchikov
Ivanovo State University of Chemistry and Technology
Email: kuvshinovae@isuct.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000