Regularities of Pd/C-catalyzed reduction of trichlorobiphenyls with 2-propanol in basic medium
- 作者: Kostenko E.1, Eliseenkov E.2, Petrov A.2
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隶属关系:
- St. Petersburg State Institute of Technology (Technical University)
- St. Petersburg State University
- 期: 卷 87, 编号 8 (2017)
- 页面: 1656-1662
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220934
- DOI: https://doi.org/10.1134/S1070363217080023
- ID: 220934
如何引用文章
详细
Reduction of a series of trichlorobiphenyls with 2-propanol in basic medium catalyzed by Pd/C has been studied. Regioselectivity of the reduction has been determined. In the studied cases, the chlorine atom in para or meta positions of the more substituted ring has been more reactive. Using isotope labeling, it has been demonstrated that the reaction occurs via the stage of 2-propanol dehydration on palladium catalyst, followed by catalytic hydrogenation of the polychlorinated biphenyls.
作者简介
E. Kostenko
St. Petersburg State Institute of Technology (Technical University)
Email: aap1947@yandex.ru
俄罗斯联邦, St. Petersburg
E. Eliseenkov
St. Petersburg State University
Email: aap1947@yandex.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Petrov
St. Petersburg State University
编辑信件的主要联系方式.
Email: aap1947@yandex.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034