Coordination of zinc tetraphenylporphyrin with pyridine derivatives in chloroform solution and in the solid phase
- 作者: Andreev V.1, Sobolev P.1, Tafeenko V.2
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隶属关系:
- Petrozavodsk State University
- Faculty of Chemistry
- 期: 卷 87, 编号 7 (2017)
- 页面: 1572-1579
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220777
- DOI: https://doi.org/10.1134/S1070363217070210
- ID: 220777
如何引用文章
详细
Coordination of zinc tetraphenylporphyrin with 2-,3-, and 4-halopyridines, pyridin-2-amine, and pyrimidin-2-amine in chloroform has been studied by spectrophotometry. Protonation and complexation of halopyridines and haloanilines with zinc tetraphenylporphyrin are discussed. According to the X-ray diffraction data, enhanced stability of the 2: 2 zinc tetraphenylporphyrin complex with pyrimidin-2-amine in the solid phase and in chloroform solution is likely to be determined by hydrogen bonding between the two ligand molecules involving nitrogen atoms in the pyrimidine ring and amino group.
作者简介
V. Andreev
Petrozavodsk State University
Email: 16862.10.ns@gmail.com
俄罗斯联邦, ul. Lenina 33, Petrozavodsk, 185910
P. Sobolev
Petrozavodsk State University
编辑信件的主要联系方式.
Email: 16862.10.ns@gmail.com
俄罗斯联邦, ul. Lenina 33, Petrozavodsk, 185910
V. Tafeenko
Faculty of Chemistry
Email: 16862.10.ns@gmail.com
俄罗斯联邦, Moscow, 119991
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