Quantum-chemical study of the reaction of N-vinylpyrrolidone with maleic anhydride
- 作者: Turina T.1, Zarechnaya O.1, Zaitseva V.1, Zaitsev S.2
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隶属关系:
- L.M. Litvinenko Institute of Physical Organic and Coal Chemistry
- K.I. Scryabin Moscow State Academy of Veterinary Medicine and Biotechnology
- 期: 卷 87, 编号 3 (2017)
- 页面: 489-498
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218816
- DOI: https://doi.org/10.1134/S1070363217030197
- ID: 218816
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详细
Energy profiles are calculated for the reaction of the structural isomer of N-vinylpyrrolidone with maleic anhydride in the gas phase. One of the reaction pathways leads to the formation and regeneration of maleic anhydride, acting as an activator of the process of (co)polymerization and dimerization of N-vinylpyrrolidone. According to calculations, the intermediate, isomer of N-vintlpyrrolidone, is a hybride of the singlet biradical and zwitter-ionic form.
作者简介
T. Turina
L.M. Litvinenko Institute of Physical Organic and Coal Chemistry
Email: valzaitseva@mail.ru
乌克兰, ul. R. Lyuksemburg 70, Donetsk, 83114
O. Zarechnaya
L.M. Litvinenko Institute of Physical Organic and Coal Chemistry
Email: valzaitseva@mail.ru
乌克兰, ul. R. Lyuksemburg 70, Donetsk, 83114
V. Zaitseva
L.M. Litvinenko Institute of Physical Organic and Coal Chemistry
编辑信件的主要联系方式.
Email: valzaitseva@mail.ru
乌克兰, ul. R. Lyuksemburg 70, Donetsk, 83114
S. Zaitsev
K.I. Scryabin Moscow State Academy of Veterinary Medicine and Biotechnology
Email: valzaitseva@mail.ru
俄罗斯联邦, Moscow