Stereoselective reactions of trivalent phosphorus compounds
- 作者: Kolodiazhnyi O.1
-
隶属关系:
- Institute of Bioorganic Chemistry and Petrochemistry
- 期: 卷 87, 编号 3 (2017)
- 页面: 425-441
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218685
- DOI: https://doi.org/10.1134/S1070363217030112
- ID: 218685
如何引用文章
详细
The data on stereoselective reactions of achiral compounds of trivalent phosphorus with chiral nucleophiles (derivatives of secondary alcohols, amines, and amino acids) are analyzed and discussed. In certain cases, these reactions enable preparation of optically active aminophosphines and phosphinites, precursors in the synthesis of chiral organophosphorus compounds and phosphine ligands. The reactions are suitable for elucidation of mechanism and stereochemistry of nucleophilic substitution at trivalent phosphorus atom.
作者简介
O. Kolodiazhnyi
Institute of Bioorganic Chemistry and Petrochemistry
编辑信件的主要联系方式.
Email: olegkol321@gmail.com
乌克兰, ul. Murmanskaya 1, Kiev, 02094