Synthesis and structure of tri(o-tolyl) antimony dioximates
- 作者: Sharutin V.1, Sharutina O.1, Artem’eva E.1, Makerova M.1
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隶属关系:
- National Research South Ural State University
- 期: 卷 86, 编号 12 (2016)
- 页面: 2671-2676
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216731
- DOI: https://doi.org/10.1134/S1070363216120161
- ID: 216731
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详细
Tri(o-tolyl) antimony dioximates were synthesized by the reaction of tri(o-tolyl) antimony with 5-nitrofurfural and thiophen-2-carbaldehyde oximes in ether in the presence of hydrogen peroxide or tert-butylhydroperoxide (1: 2: 1 mol). Antimony atoms in the reaction products have distorted trigonal-bipyramidal coordination with the intramolecular distances Sb···N shorter than the sum of the van der Waals radii of Sb and N by ~1 Å.
作者简介
V. Sharutin
National Research South Ural State University
编辑信件的主要联系方式.
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
National Research South Ural State University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
E. Artem’eva
National Research South Ural State University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
M. Makerova
National Research South Ural State University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
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