On hydrolysis of Ba–Bi–O and K–Ba–Bi–O oxide systems
- 作者: Barkovskii N.1
-
隶属关系:
- Institute of Solid State Physics
- 期: 卷 86, 编号 8 (2016)
- 页面: 1787-1793
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215894
- DOI: https://doi.org/10.1134/S1070363216080028
- ID: 215894
如何引用文章
详细
Fundamentally different behavior of Ba–Bi–O (Ba : Bi = 11 : 4, 1 : 1, 2: 3, and 1 : 5 mol/mol) and KnBamBim+nOy (m = n = 1, 2,...; exhibiting superconducting properties with Tc = 28–32 K) oxides and BaO2 in hydrolysis reactions has been revealed by means of potentiometry and chemical analysis. Products of the oxides treatment with water do not contain H2O2, evidencing the absence of peroxide ions in their structure. The perovskite-type barium-bismuth(III) oxides are completely hydrolyzed into Ba(OH)2 and Bi2O3 at room temperature.
作者简介
N. Barkovskii
Institute of Solid State Physics
编辑信件的主要联系方式.
Email: barkov@issp.ac.ru
俄罗斯联邦, ul. Akademika Osipyana 2, Chernogolovka, 142432