Iron compounds in controlled radical polymerization: Ferrocenes, (clathro)chelates, and porphyrins
- 作者: Islamova R.1
-
隶属关系:
- St. Petersburg State University
- 期: 卷 86, 编号 1 (2016)
- 页面: 125-143
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213478
- DOI: https://doi.org/10.1134/S1070363216010217
- ID: 213478
如何引用文章
详细
Experimental data on the application of metal complexes in radical polymerization of vinyl monomers collected over the recent 15 years have been analyzed and generalized. Special attention has been given to (un)substituted ferrocenes, macrocyclic (clathro)chelates, and iron porphyrinates as well as to the approaches to enhance their catalytic activity in controlled synthesis of macromolecules. The mentioned systems have been compared with each other as well as with selected complexes of other transition metals. It has been shown that the electronic and spatial structures of the metal complexes are related to their efficiency in the radical polymerization reactions.
作者简介
R. Islamova
St. Petersburg State University
编辑信件的主要联系方式.
Email: r.islamova@spbu.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
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