Redox reactions involving Ce3+ cations and FeO42– anions and the synthesis of Ce1.1FeOx·nH2O nanolayers by the SILD method
- 作者: Kuklo L.1, Tolstoy V.1
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隶属关系:
- St. Petersburg State University
- 期: 卷 86, 编号 1 (2016)
- 页面: 1-4
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213396
- DOI: https://doi.org/10.1134/S1070363216010011
- ID: 213396
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详细
Conditions for the synthesis of nanolayers of cerium and iron binary oxides by the successive ionic layer deposition (SILD) method based on consecutive and repeated realization of redox reactions in a layer of adsorbed Ce3+ cations and FeO42– anions on a substrate surface were considered. The synthesized layers were studied by scanning electron microscopy, X-ray spectral microanalysis, IR-Fourier and X-ray photoelectron spectroscopy, and also by X-ray diffraction methods. Under conditions of the synthesis layers of the hydrated amorphous oxide Ce1.1FeOx·nH2O containing Ce(IV) and Fe(III) atoms in the ratio 1.1 : 1.0 are formed on the surface.
作者简介
L. Kuklo
St. Petersburg State University
Email: vptol@yandex.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034
V. Tolstoy
St. Petersburg State University
编辑信件的主要联系方式.
Email: vptol@yandex.ru
俄罗斯联邦, Universitetskaya nab. 7–9, St. Petersburg, 199034