Isoenthalpy Catalytic Effects of Pyridines in Reactions of Phenyloxyrane with N-Aroylbenzenesulfonamides
- Авторы: Shpanko I.1, Sadovaya I.2
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Учреждения:
- V. Stus Donetsk National University
- Donetsk National University
- Выпуск: Том 89, № 12 (2019)
- Страницы: 2358-2363
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223188
- DOI: https://doi.org/10.1134/S1070363219120053
- ID: 223188
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Аннотация
Additive nature of the combined effect of the structure (X, Y substituents) and temperature on the rate and free activation energy has been established for the reactions of phenyloxirane with Y-substituted N-aroylbenzenesulfonamides catalyzed by X-substituted pyridines. The cross reaction series is isoenthalpic with respect to the structural effects. The mechanism of the catalytic process has been discussed.
Об авторах
I. Shpanko
V. Stus Donetsk National University
Автор, ответственный за переписку.
Email: shpanko16@ukr.net
Украина, Vinnitsa, 21021
I. Sadovaya
Donetsk National University
Email: shpanko16@ukr.net
Украина, Donetsk