Investigation of Acidic and Coordination Properties of Octabromo-Substituted Porphyrins in the System of 1,8-Diazabicyclo[5,4,0]unde-7-ene-Acetonitrile
- Авторы: Pukhovskaya S.1, Ivanova Y.2, Semeikin A.1, Syrbu S.1, Kruk N.3
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Учреждения:
- Ivanovo State University of Chemistry and Technology
- G.A. Krestov Institute of Solution Chemistry
- Belarusian State Technological University
- Выпуск: Том 89, № 6 (2019)
- Страницы: 1286-1296
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222961
- DOI: https://doi.org/10.1134/S1070363219060252
- ID: 222961
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Аннотация
Acidity and metal ion coordination are described for three porphyrin derivatives, different in their macrocycle conformation and electronic substitution effects due to bromine substitution in pyrrole rings and trifluorometyl or phenyl groups in meso-positions. Combination of these facts allows modulating both steric and electronic effects on the macrocycle π-conjugated system. The role of electronic substitution effects in the macrocycle deprotonation and metal ion complex formation is found dominating with comparable resonance and inductive contributions, whereas non-planar conformation of reactive species contributes to the reaction rates to a lesser extent. The interaction of two single-electron (a1ueg) and (a2ueg) configurations is studied as a function of non-planar distortions of the molecular structure for the three tetrapyrrole compounds. The additive influence of disturbing factors on the configuration interaction of single-electron (a1ueg) and (a2ueg) configurations in the tetrapyrrole macrocycle is demonstrated.
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Об авторах
S. Pukhovskaya
Ivanovo State University of Chemistry and Technology
Автор, ответственный за переписку.
Email: svetlana.puhovskaya@mail.ru
Россия, pr. Sheremetevskii 7, Ivanovo, 153460
Yu. Ivanova
G.A. Krestov Institute of Solution Chemistry
Автор, ответственный за переписку.
Email: jjiv@yandex.ru
Россия, ul. Akademicheskaya 1, Ivanovo, 153045
A. Semeikin
Ivanovo State University of Chemistry and Technology
Email: krukmikalai@yahoo.com
Россия, pr. Sheremetevskii 7, Ivanovo, 153460
S. Syrbu
Ivanovo State University of Chemistry and Technology
Email: krukmikalai@yahoo.com
Россия, pr. Sheremetevskii 7, Ivanovo, 153460
N. Kruk
Belarusian State Technological University
Автор, ответственный за переписку.
Email: krukmikalai@yahoo.com
Белоруссия, ul. Sverdlova 13a, Minsk, 220006
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