Sorption and Selective Properties of Diatomite Adsorbents for Gas Chromatography, Modified by a Cu(II) Complex of a Camphor-Substituted Tetrapyrasinoporphyrazine
- Авторы: Kuvshinov G.1, Koifman O.1,2
-
Учреждения:
- Ivanovo State University of Chemical Technology (ISUCT)
- Krestov Institute of Solution Chemistry
- Выпуск: Том 89, № 6 (2019)
- Страницы: 1279-1285
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222959
- DOI: https://doi.org/10.1134/S1070363219060240
- ID: 222959
Цитировать
Аннотация
Modified adsorbents for gas chromatography were prepared using a Cu(II) complex of a camphorsabstituted tetrapyrasinoporphyrazine. The thermal stability of phthalocyanines and modified adsorbents was studied by thermogravimetry. The adsorption of a series of organic compounds from the gas phase on the surface of the modified sorbents was studied by gas chromatography. Electron-donor methylpyridine and dimethylpyridine isomers and low-polar xylene and alcohol isomers were used as sorbates. Specific retention volumes of sorbates and separation factors of close-boiling hydrocarbons were calculated. The sorbents on the basis of Cu(II) tetra(1′,7′,7′-trimethylbicyclo[2.2.1]heptano[2′,3′-b]pyrazino)porphyrazine exhibit a high selectivity to closely boiling organic compounds of different classes and a high efficiency in their separation.
Ключевые слова
Об авторах
G. Kuvshinov
Ivanovo State University of Chemical Technology (ISUCT)
Email: koifman@isuct.ru
Россия, pr. Sheremetevskii 7, Ivanovo, 15300
O. Koifman
Ivanovo State University of Chemical Technology (ISUCT); Krestov Institute of Solution Chemistry
Автор, ответственный за переписку.
Email: koifman@isuct.ru
Россия, pr. Sheremetevskii 7, Ivanovo, 15300; ul. Akademicheskaya 1, Ivanovo, 153040