Synthesis of Cu@Ag Nanoparticles with a Core–Shell Structure Stabilized with Oxyethylated Carboxylic Acid
- Авторы: Titkov A.1, Logutenko O.1, Vorob’yov A.1, Gerasimov E.2, Bulina N.1, Yukhin Y.1, Lyakhov N.1
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Учреждения:
- Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
- G.K. Boreskov Institute of Catalysis, Siberian Branch
- Выпуск: Том 89, № 1 (2019)
- Страницы: 100-105
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222712
- DOI: https://doi.org/10.1134/S1070363219010183
- ID: 222712
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Аннотация
Bimetallic Cu@Ag nanoparticles with a core–shell structure were synthesized by reduction of copper 2-[2-(2-methoxyethoxy)ethoxy]acetate with hydrazine hydrate in benzyl alcohol, followed by reducing the silver ions on the copper surface by transmetallation reaction. The sinthesized nanoparticles were characterized by X-ray diffraction, transmission electron microscopy, and optical spectroscopy methods. The effect of the synthesis conditions such as temperature, time, Ag: Cu molar ratio, the rate of silver nitrate addition, on the uniformity of silver coating on the surface of copper nuclei was studied.
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Об авторах
A. Titkov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: ologutenko@solid.nsc.ru
Россия, ul. Kutateladze 18, Novosibirsk, 630128
O. Logutenko
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Автор, ответственный за переписку.
Email: ologutenko@solid.nsc.ru
Россия, ul. Kutateladze 18, Novosibirsk, 630128
A. Vorob’yov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: ologutenko@solid.nsc.ru
Россия, ul. Kutateladze 18, Novosibirsk, 630128
E. Gerasimov
G.K. Boreskov Institute of Catalysis, Siberian Branch
Email: ologutenko@solid.nsc.ru
Россия, Novosibirsk
N. Bulina
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: ologutenko@solid.nsc.ru
Россия, ul. Kutateladze 18, Novosibirsk, 630128
Yu. Yukhin
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: ologutenko@solid.nsc.ru
Россия, ul. Kutateladze 18, Novosibirsk, 630128
N. Lyakhov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: ologutenko@solid.nsc.ru
Россия, ul. Kutateladze 18, Novosibirsk, 630128
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