Synthesis, Structure, and X-Ray Photoelectron Spectra of Cobalt and Copper Complexes with 2-{(E)-[2-(4-Hydroxybutylamino)benzimidazol-1-yl]iminomethyl}phenol
- Авторы: Vlasenko V.1, Burlov A.2, Kuz’menko T.2, Kozakov A.1, Nikol’skii A.1, Trigub A.3, Levchenkov S.4
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Учреждения:
- Research Institute of Physics
- Research Institute of Physical and Organic Chemistry
- “Kurchatov Institute”
- Southern Research Center
- Выпуск: Том 88, № 12 (2018)
- Страницы: 2550-2558
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222591
- DOI: https://doi.org/10.1134/S1070363218120150
- ID: 222591
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Аннотация
A new azomethine compound, 2-{(E)-[2-(4-hydroxybutylamino)benzimidazol-1-yl]iminomethyl}- phenol, and its cobalt(II) and copper(II) complexes were synthesized and characterized by IR, 1Н NMR, and X-ray photoelectron spectroscopy and quantum-chemical calculations. The crystal and molecular structures of the cobalt complex were established by X-ray diffraction analysis. The oxidation state of the cobalt ion in the complex after its crystallization from the solution was defined more exactly by X-ray photoelectron spectroscopy.
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Об авторах
V. Vlasenko
Research Institute of Physics
Автор, ответственный за переписку.
Email: v_vlasenko@rambler.ru
Россия, pr. Stachki 194, Rostov-on-Don, 344090
A. Burlov
Research Institute of Physical and Organic Chemistry
Email: v_vlasenko@rambler.ru
Россия, Rostov-on-Don
T. Kuz’menko
Research Institute of Physical and Organic Chemistry
Email: v_vlasenko@rambler.ru
Россия, Rostov-on-Don
A. Kozakov
Research Institute of Physics
Email: v_vlasenko@rambler.ru
Россия, pr. Stachki 194, Rostov-on-Don, 344090
A. Nikol’skii
Research Institute of Physics
Email: v_vlasenko@rambler.ru
Россия, pr. Stachki 194, Rostov-on-Don, 344090
A. Trigub
“Kurchatov Institute”
Email: v_vlasenko@rambler.ru
Россия, Moscow
S. Levchenkov
Southern Research Center
Email: v_vlasenko@rambler.ru
Россия, Rostov-on-Don