Compounds of potassium and tin(II) with diiminopyridine ligands: EPR spectroscopy and theoretical study
- Авторы: Chegerev M.1, Piskunov A.1, Starikova A.2
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Учреждения:
- Razuvaev Institute of Organometallic Chemistry
- Research Institute of Physical and Organic Chemistry
- Выпуск: Том 87, № 11 (2017)
- Страницы: 2582-2588
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221568
- DOI: https://doi.org/10.1134/S1070363217110111
- ID: 221568
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Аннотация
Potassium and tin(II) derivatives of the paramagnetic forms of the redox-active 2,6-bis(2,6-diisopropylphenyliminomethyl)pyridine were synthesized and studied by means of EPR spectroscopy. It was shown that the reaction with metallic potassium involves the three-electron step reduction of the organic ligand to form a radical anion, dianion, and trianion radical, respectively. The reactions of the tin(II) diiminopyridine derivatives with metallic magnesium give complexes comprising the radical anion form of the ligand and a low-valence metal center. The geometries of the paramagnetic products and their spin density distributions were explored in terms of the density functional theory.
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M. Chegerev
Razuvaev Institute of Organometallic Chemistry
Email: pial@iomc.ras.ru
Россия, ul. Tropinina 49, Nizhny Novgorod, 603950
A. Piskunov
Razuvaev Institute of Organometallic Chemistry
Автор, ответственный за переписку.
Email: pial@iomc.ras.ru
Россия, ul. Tropinina 49, Nizhny Novgorod, 603950
A. Starikova
Research Institute of Physical and Organic Chemistry
Email: pial@iomc.ras.ru
Россия, Rostov-on-Don