Colloidal and Nanosized Catalysts in Organic Synthesis: XXIII. Reductive Amination of Carbonyl Compounds Catalyzed by Nickel Nanoparticles in a Plug-Flow Reactor

V. M. Mokhov; Yu. V. Popov; A. N. Paputina; D. N. Nebykov; E. V. Shishkin

doi:10.1134/S1070363219120016

Colloidal and Nanosized Catalysts in Organic Synthesis: XXIII. Reductive Amination of Carbonyl Compounds Catalyzed by Nickel Nanoparticles in a Plug-Flow Reactor

Autores: Mokhov V.¹, Popov Y.¹, Paputina A.¹, Nebykov D.¹, Shishkin E.¹
Afiliações:
1. Volgograd State Technical University
Edição: Volume 89, Nº 12 (2019)
Páginas: 2333-2340
Seção: Article
URL: https://journals.rcsi.science/1070-3632/article/view/223183
DOI: https://doi.org/10.1134/S1070363219120016
ID: 223183

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Resumo

Reductive amination of aldehydes and ketones with primary and secondary amines under catalysis with nickel nanoparticles supported on zeolite X, MgO, or activated carbon in the gas phase or in the gas-liquid system in a plug-flow reactor proceeds at atmospheric pressure of hydrogen with the formation of secondary or tertiary amines in high yield.