Synthesis and Some Transformations of 7-Substituted 8-Chlorotheophyllines

K. Yu. Petrova; D. G. Kim; V. V. Sharutin; O. S. Eltsov; T. S. Shtukina; A. A. Anuchin

doi:10.1134/S1070363219110069

Synthesis and Some Transformations of 7-Substituted 8-Chlorotheophyllines

Autores: Petrova K.¹, Kim D.¹, Sharutin V.¹, Eltsov O.², Shtukina T.², Anuchin A.³
Afiliações:
1. South Ural State University (NRU)
2. Ural Federal University
3. Criminalistics Laboratory of Police Department of Chelyabinsk Region
Edição: Volume 89, Nº 11 (2019)
Páginas: 2201-2206
Seção: Article
URL: https://journals.rcsi.science/1070-3632/article/view/223151
DOI: https://doi.org/10.1134/S1070363219110069
ID: 223151

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Alkylation of 8-chlorotheophylline by alkenyl(propargyl) halides yields 7-alkenyl(propargyl)-8-chlorotheophyllines. The reaction of 8-chlorotheophylline with 1,3-dichloropropan-2-ol leads to the formation of oxazolo[2,3-f]purinium system. 7-Alkenyl-8-chlorotheophyllines react with bromine to give dibromoalkyl-8-chlorotheophyllines. The reaction of 7-methallyl-8-chlorotheophylline with m-chloroperbenzoic acid affords the corresponding oxirane.