Study of the Kinetics of Esterification of Dichloromaleic Anhydride with Methanol in the Presence of Zeolitic Catalysts

I. G. Melikova; A. D. Efendi; B. A. Ismailova; G. M. Faradzhev; L. G. Magerramova; K. I. Gadzhieva

doi:10.1134/S1070363218120058

Study of the Kinetics of Esterification of Dichloromaleic Anhydride with Methanol in the Presence of Zeolitic Catalysts

Autores: Melikova I.¹, Efendi A.¹, Ismailova B.¹, Faradzhev G.¹, Magerramova L.¹, Gadzhieva K.¹
Afiliações:
1. Nagiev Institute of Catalysis and Inorganic Chemistry
Edição: Volume 88, Nº 12 (2018)
Páginas: 2480-2485
Seção: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222577
DOI: https://doi.org/10.1134/S1070363218120058
ID: 222577

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Resumo

Kinetics and mechanism of esterification of dichloromaleic anhydride with C₁–C₄ alcohols in the presence of zeolitic catalysts have been studied. The stage-by-stage Langmuir–Hinshelwood mechanism of heterogeneous catalysis at acidic active surface sites of zeolites has been suggested. The kinetic model has been elaborated, the parameters of the experimental data fitting have been calculated.