Phosphorylation of Betti Base with Bis(diethylamino)phosphoryl Chloride
- Autores: Metlushka K.1, Sadkova D.1, Nikitina K.1, Yamaleeva Z.1, Ivshin K.1,2, Kataeva O.1, Alfonsov V.1
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Afiliações:
- A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center
- Butlerov Chemical Institute
- Edição: Volume 88, Nº 11 (2018)
- Páginas: 2453-2456
- Seção: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222570
- DOI: https://doi.org/10.1134/S1070363218110348
- ID: 222570
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Resumo
The reaction of bis(diethylamino)phosphoryl chloride with N-Boc-protected 1-(α-aminobenzyl)-2- naphthol (Betti base) proceeded via O-phosphorylation of the phenolic OH group to form the target product as trifluoroacetate salt. The latter reacted with O,O-diethyl thiophosphorylisothiocyanate to give thiourea bearing a chiral Betti base fragment.
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Sobre autores
K. Metlushka
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center
Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
D. Sadkova
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center
Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
K. Nikitina
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center
Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
Z. Yamaleeva
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center
Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
K. Ivshin
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center; Butlerov Chemical Institute
Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan
O. Kataeva
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center
Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. Alfonsov
A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center
Autor responsável pela correspondência
Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
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