Phosphorylation of Betti Base with Bis(diethylamino)phosphoryl Chloride


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Resumo

The reaction of bis(diethylamino)phosphoryl chloride with N-Boc-protected 1-(α-aminobenzyl)-2- naphthol (Betti base) proceeded via O-phosphorylation of the phenolic OH group to form the target product as trifluoroacetate salt. The latter reacted with O,O-diethyl thiophosphorylisothiocyanate to give thiourea bearing a chiral Betti base fragment.

Sobre autores

K. Metlushka

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

D. Sadkova

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

K. Nikitina

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

Z. Yamaleeva

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

K. Ivshin

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center; Butlerov Chemical Institute

Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan

O. Kataeva

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

V. Alfonsov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Autor responsável pela correspondência
Email: alfonsov@yandex.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088


Declaração de direitos autorais © Pleiades Publishing, Ltd., 2018

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