Basic and Coordination Properties of Tetraphenylporphine Derivatives
- Autores: Ivanova Y.1, Plotnikova A.2, Semeikin A.2, Pukhovskaya S.2, Mamardashvili N.1
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Afiliações:
- Krestov Institute of Solutions Chemistry
- Ivanovo State University of Chemistry and Technology
- Edição: Volume 88, Nº 10 (2018)
- Páginas: 2103-2107
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222475
- DOI: https://doi.org/10.1134/S1070363218100122
- ID: 222475
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Resumo
Basic and coordination properties of 5,10,15,20-tetrakis(3,5-dibromophenyl)porphine and 5,10,15,20-tetrakis(4-methoxy-3-bromophenyl)porphine in acetonitrile have been investigated by means of spectrophotometry. The optimization of the geometry parameters of polysubstituted porphyrins has been performed using quantum-chemical method (РМ3). The relationship between geometric structure of the studied porphyrins and their coordination, basic, and spectral properties is discussed.
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Sobre autores
Yu. Ivanova
Krestov Institute of Solutions Chemistry
Autor responsável pela correspondência
Email: jjiv@yandex.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153045
A. Plotnikova
Ivanovo State University of Chemistry and Technology
Email: jjiv@yandex.ru
Rússia, Ivanovo
A. Semeikin
Ivanovo State University of Chemistry and Technology
Email: jjiv@yandex.ru
Rússia, Ivanovo
S. Pukhovskaya
Ivanovo State University of Chemistry and Technology
Email: jjiv@yandex.ru
Rússia, Ivanovo
N. Mamardashvili
Krestov Institute of Solutions Chemistry
Email: jjiv@yandex.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153045