Allobetulin Ring A Contraction Effected by Sulfur Diethylaminotrifluoride
- Autores: Fedorov A.1, Samoilenko D.1, Shafeeva M.1, Abzianidze V.2, Trishin Y.1
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Afiliações:
- High School of Technology and Energetics
- Research Institute of Hygiene, Toxicology, and Occupational Pathology
- Edição: Volume 88, Nº 9 (2018)
- Páginas: 1948-1950
- Seção: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222441
- DOI: https://doi.org/10.1134/S1070363218090347
- ID: 222441
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Resumo
The action of sulfur diethylaminotrifluoride on 19β,28-epoxyoleanan-3-ol (allobetulin) causes dehydration of the terpenoid and isomerization of the ring A via its contraction to isopropylcyclopentene ring resulting in 19β,28-epoxy-A-neo-18α-olean-3(5)-ene (α-allobetulin) in a high yield.
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Sobre autores
A. Fedorov
High School of Technology and Energetics
Email: trish@YT4470.spb.edu
Rússia, ul. Ivana Chernykh 4, St. Petersburg, 198095
D. Samoilenko
High School of Technology and Energetics
Email: trish@YT4470.spb.edu
Rússia, ul. Ivana Chernykh 4, St. Petersburg, 198095
M. Shafeeva
High School of Technology and Energetics
Email: trish@YT4470.spb.edu
Rússia, ul. Ivana Chernykh 4, St. Petersburg, 198095
V. Abzianidze
Research Institute of Hygiene, Toxicology, and Occupational Pathology
Email: trish@YT4470.spb.edu
Rússia, Kuzmolovskii
Yu. Trishin
High School of Technology and Energetics
Autor responsável pela correspondência
Email: trish@YT4470.spb.edu
Rússia, ul. Ivana Chernykh 4, St. Petersburg, 198095
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