Formation of the P–C and C–C bonds in the Reaction of 2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one with Dimethyl Acetylenedicarboxylate under Mild Conditions
- Autores: Mironov V.1,2, Ivkova G.2, Musin R.1, Abdrakhmanova L.1
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Afiliações:
- Arbuzov Institute of Organic and Physical Chemistry
- Kazan (Volga Region) Federal University
- Edição: Volume 88, Nº 3 (2018)
- Páginas: 605-606
- Seção: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222109
- DOI: https://doi.org/10.1134/S1070363218030350
- ID: 222109
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Resumo
2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one reacts under mild conditions with dimethyl acetylenedicarboxylate with the participation by only threecoordinated phosphorus atom and the formation of 2-(5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-3,4-dimethoxycarbonylbenzo[f]-1,2-oxaphosphepine-2,5-dione. During the process, simultaneous formation of the P–C and C–C bonds takes place.
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Sobre autores
V. Mironov
Arbuzov Institute of Organic and Physical Chemistry; Kazan (Volga Region) Federal University
Autor responsável pela correspondência
Email: mironov@iopc.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088; Kazan, Tatarstan
G. Ivkova
Kazan (Volga Region) Federal University
Email: mironov@iopc.ru
Rússia, Kazan, Tatarstan
R. Musin
Arbuzov Institute of Organic and Physical Chemistry
Email: mironov@iopc.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
L. Abdrakhmanova
Arbuzov Institute of Organic and Physical Chemistry
Email: mironov@iopc.ru
Rússia, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088