Pd2+-Catalyzed Addition of 1-Substituted Tetrazole-5-thiols to Terminal Acetylenes in Acid Medium


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Resumo

Addition of 1-substituted tetrazole-5-thiols to ethyl propiolate and phenylacetylene was studied. It was found that Pd(II) salts in the presence of strong acids are effective catalysts for this reaction: the S-adducts can be obtained at relatively low temperatures in high yields. The mechanism of this reaction was suggested.

Sobre autores

L. Myznikov

St. Petersburg State University of Industrial Technology and Design

Autor responsável pela correspondência
Email: myznikov_lv@mail.ru
Rússia, ul. Bolshaya Morskaya 18, St. Petersburg, 191186

Yu. Melnikova

St. Petersburg State University of Industrial Technology and Design; Novbytkhim Company

Email: myznikov_lv@mail.ru
Rússia, ul. Bolshaya Morskaya 18, St. Petersburg, 191186; St. Petersburg

R. Baichurin

Herzen State Pedagogical University of Russia

Email: myznikov_lv@mail.ru
Rússia, St. Petersburg

T. Artamonova

St. Petersburg State University of Industrial Technology and Design

Email: myznikov_lv@mail.ru
Rússia, ul. Bolshaya Morskaya 18, St. Petersburg, 191186

Yu. Zevatskii

St. Petersburg State University of Industrial Technology and Design; Novbytkhim Company

Email: myznikov_lv@mail.ru
Rússia, ul. Bolshaya Morskaya 18, St. Petersburg, 191186; St. Petersburg


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