Synthesis and properties of 2,5-bis(furan-2-yl)-1H-imidazole
- Autores: El’chaninov M.1, Vlasova E.1, El’chaninov I.1
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Afiliações:
- Platov South-Russian State Polytechnic University
- Edição: Volume 87, Nº 2 (2017)
- Páginas: 239-243
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218224
- DOI: https://doi.org/10.1134/S1070363217020141
- ID: 218224
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Resumo
2,5-Bis(furan-2-yl)-1H-imidazole was synthesized by the Weidenhagen reaction of [2-(furan-2-yl)-2-oxoethyl]acetate with furfural. Alkylation of the title compound with methyl iodide in acetone in the presence of potassium hydroxide gave a mixture of isomeric N-methyl derivatives, 2,5-bis(furan-2-yl)-1-methyl-1H-imidazole being the major one. Electrophilic substitution reactions of the latter (nitration, bromination, sulfonation, hydroxymethylation, and acylation) were studied.
Sobre autores
M. El’chaninov
Platov South-Russian State Polytechnic University
Autor responsável pela correspondência
Email: elchaninov-43@mail.ru
Rússia, pr. Prosveshcheniya 132, Novocherkassk, 346428
E. Vlasova
Platov South-Russian State Polytechnic University
Email: elchaninov-43@mail.ru
Rússia, pr. Prosveshcheniya 132, Novocherkassk, 346428
I. El’chaninov
Platov South-Russian State Polytechnic University
Email: elchaninov-43@mail.ru
Rússia, pr. Prosveshcheniya 132, Novocherkassk, 346428