Synthesis, structure, and photoluminescence properties of N-{2-[5-(2-hydroxyphenylmethyleneamino)-1-alkylbenzimidazol-2-yl]phenyl}-4-methylbenzenesulfamides and their zinc complexes
- Autores: Koshchienko Y.1, Burlov A.1, Makarova N.1, Vlasenko V.2, Nikolaevskii S.3, Kiskin M.3, Alexandrov G.3, Garnovskii D.4, Metelitsa A.1, Minkin V.1
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Afiliações:
- Institute of Physical and Organic Chemistry of Southern Federal University
- Institute of Physics of Southern Federal University
- N.S. Kurnakov Institute of General and Inorganic Chemistry
- Southern Scientific Centre Academy of Sciences
- Edição: Volume 87, Nº 1 (2017)
- Páginas: 76-85
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217885
- DOI: https://doi.org/10.1134/S1070363217010133
- ID: 217885
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Resumo
N-{2-[5-(2-Hydroxyphenylmethyleneamino)-1-alkylbenzimidazol-2-yl]phenyl}-4-methyl-benzenesulfamides (H2L) and their zinc complexes Zn2L2 were synthesized. The structure of the ligands and complexes was studied by IR, UV, 1Н NMR, X-ray absorption spectroscopy, and X-ray diffraction analysis. The complexes show green photoluminescence (λfl = 492 nm) with quantum yields φ = 0.07–0.17.
Sobre autores
Yu. Koshchienko
Institute of Physical and Organic Chemistry of Southern Federal University
Email: anatoly.burlov@yandex.ru
Rússia, pr. Stachki 194/2, Rostov-on-Don, 344090
A. Burlov
Institute of Physical and Organic Chemistry of Southern Federal University
Autor responsável pela correspondência
Email: anatoly.burlov@yandex.ru
Rússia, pr. Stachki 194/2, Rostov-on-Don, 344090
N. Makarova
Institute of Physical and Organic Chemistry of Southern Federal University
Email: anatoly.burlov@yandex.ru
Rússia, pr. Stachki 194/2, Rostov-on-Don, 344090
V. Vlasenko
Institute of Physics of Southern Federal University
Email: anatoly.burlov@yandex.ru
Rússia, Rostov-on-Don
S. Nikolaevskii
N.S. Kurnakov Institute of General and Inorganic Chemistry
Email: anatoly.burlov@yandex.ru
Rússia, Moscow
M. Kiskin
N.S. Kurnakov Institute of General and Inorganic Chemistry
Email: anatoly.burlov@yandex.ru
Rússia, Moscow
G. Alexandrov
N.S. Kurnakov Institute of General and Inorganic Chemistry
Email: anatoly.burlov@yandex.ru
Rússia, Moscow
D. Garnovskii
Southern Scientific Centre Academy of Sciences
Email: anatoly.burlov@yandex.ru
Rússia, Rostov-on-Don
A. Metelitsa
Institute of Physical and Organic Chemistry of Southern Federal University
Email: anatoly.burlov@yandex.ru
Rússia, pr. Stachki 194/2, Rostov-on-Don, 344090
V. Minkin
Institute of Physical and Organic Chemistry of Southern Federal University
Email: anatoly.burlov@yandex.ru
Rússia, pr. Stachki 194/2, Rostov-on-Don, 344090