Transition metal chelates: Synthesis, physicochemical, thermal, and biological studies
- Autores: Suryawanshi N.1, Pethe G.2, Yaul A.2, Aswar A.2
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Afiliações:
- Department of Industrial Chemistry
- Department of Chemistry
- Edição: Volume 86, Nº 4 (2016)
- Páginas: 901-906
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214708
- DOI: https://doi.org/10.1134/S1070363216040241
- ID: 214708
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Resumo
The transition metal complex of Mn(II), Co(II), Ni(II), Cu(II), Ti(III), Cr(III), Fe(III), Zr(IV), and UO2(VI) ion with a Schiff’s base ligand derived from 2-hydroxy-[2-oxo-1,2-dihydro-3H-indol-3-ylidene]-benzohydrazide have been prepared. The complexes have been characterized by elemental analysis data, IR and electronic absorption spectra, magnetic moments, and thermogravimetric analysis data. The complexes of the 1: 1 metal-to-ligand stoichiometry have been formed. The physico-chemical data have suggested the octahedral geometry for all the complexes except for Cu(II); the Cu(II) complex has been square planar. Thermal analysis data of the ligand and its complexes have been analyzed, and the kinetic parameters have been determined using the Horowitz–Metzger method. According to the solid-state electrical conductivity measurements, the ligand and its complexes are semiconducting in nature. The antimicrobial activity of the ligand and the complexes towards E. coli, S. typhi, P. aeruginosa, and S. aureus has been tested by the disc diffusion method.
Sobre autores
N. Suryawanshi
Department of Industrial Chemistry
Email: aswar2341@rediffmail.com
Índia, Chikhaldara, 444807
G. Pethe
Department of Chemistry
Email: aswar2341@rediffmail.com
Índia, Amravati, 444602
A. Yaul
Department of Chemistry
Email: aswar2341@rediffmail.com
Índia, Amravati, 444602
A. Aswar
Department of Chemistry
Autor responsável pela correspondência
Email: aswar2341@rediffmail.com
Índia, Amravati, 444602