Colloid and nanosized catalysts in organic synthesis: XIV. Reductive amination and amidation of carbonitriles catalyzed by nickel nanoparticles
- Autores: Popov Y.1, Mokhov V.1, Shcherbakova K.1
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Afiliações:
- Volgograd State Technical University
- Edição: Volume 86, Nº 4 (2016)
- Páginas: 798-805
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214595
- DOI: https://doi.org/10.1134/S107036321604006X
- ID: 214595
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Resumo
Hydrogenation of carbonitriles catalyzed by nickel nanoparticles in the presence of primary amines led to the predominant formation of unsymmetrical secondary amines. In the presence of secondary amines hydrogenation of nitrites provided enamines as main products. Hydrogenation of nitriles in the presence of formamide or acetamide afforded formyl or acetyl derivatives of primary amines.
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Sobre autores
Yu. Popov
Volgograd State Technical University
Autor responsável pela correspondência
Email: tons@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400131
V. Mokhov
Volgograd State Technical University
Email: tons@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400131
K. Shcherbakova
Volgograd State Technical University
Email: tons@vstu.ru
Rússia, pr. Lenina 28, Volgograd, 400131
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