Tetrasubstituted Phthalocyanines with Benzoic Acids Moieties
- Авторлар: Kuznetsova D.1, Tikhomirova T.1, Maizlish V.1, Shaposhnikov G.1
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Мекемелер:
- Research Institute of Macroheterocycles
- Шығарылым: Том 89, № 6 (2019)
- Беттер: 1297-1306
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222963
- DOI: https://doi.org/10.1134/S1070363219060264
- ID: 222963
Дәйексөз келтіру
Аннотация
Phthalonitriles substituted with o-hydroxybenzoic, o-aminobenzoic, and o-mercaptobenzoic acids moieties were synthesized by nucleophilic substitution of bromine in 4-bromophthalonitrile and of nitro group in 4-nitrophthalonitrile. Template condensation of these phthalonitriles with metal acetates gave the corresponding phthalocyanines. Metal-free phthalocyanines were synthesized by dissociation of the magnesium complexes of the substituted phthalocyanines in a sulfuric acid medium. Treatment of the resultant phthalocyanines with sodium ethoxide in ethanol yielded sodium salts of the carboxylic acids. The spectral properties of the compounds synthesized were examined.
Негізгі сөздер
Авторлар туралы
D. Kuznetsova
Research Institute of Macroheterocycles
Хат алмасуға жауапты Автор.
Email: dashaf305@mail.ru
Ресей, Sheremetevskii pr. 7, Ivanovo, 153000
T. Tikhomirova
Research Institute of Macroheterocycles
Хат алмасуға жауапты Автор.
Email: tararjkina@mail.ru
Ресей, Sheremetevskii pr. 7, Ivanovo, 153000
V. Maizlish
Research Institute of Macroheterocycles
Хат алмасуға жауапты Автор.
Email: maizlish@isuct.ru
Ресей, Sheremetevskii pr. 7, Ivanovo, 153000
G. Shaposhnikov
Research Institute of Macroheterocycles
Хат алмасуға жауапты Автор.
Email: ttoc@isuct.ru
Ресей, Sheremetevskii pr. 7, Ivanovo, 153000