Synthesis, Interatomic Interactions, Structure, and Conductivity of Lanthanum Gallate Doped with Nickel and Magnesium
- Авторлар: Korolev D.1, Chezhina N.1, Glumov O.1
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Мекемелер:
- St. Petersburg State University
- Шығарылым: Том 89, № 6 (2019)
- Беттер: 1129-1135
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222932
- DOI: https://doi.org/10.1134/S1070363219060069
- ID: 222932
Дәйексөз келтіру
Аннотация
The coexistence of two crystal modifications of lanthanum gallate, orthorhombic and rhombohedral, was revealed for the first time in two series of solutions: LaNixMg0.2xGa1–1.2xO3−δ ([Ni]: [Mg] = 5: 1) and LaNixMg0.5xGa1–15xO3−δ ([Ni]: [Mg] = 2: 1), x = 0.01–0.10. The unit cell parameters in the both series of solid solutions were refined by the Rietveld method. The magnetic susceptibility measurements point to the presence of clusters of Ni(III) atoms with strong antiferromagnetic interactions. The conductivity measurements point to high conductivity values for the system with the ratio [Ni]: [Mg] = 5 : 1.
Авторлар туралы
D. Korolev
St. Petersburg State University
Хат алмасуға жауапты Автор.
Email: d.korolev@spbu.ru
Ресей, Universitetskaya nab. 7-9, St. Petersburg, 199034
N. Chezhina
St. Petersburg State University
Email: d.korolev@spbu.ru
Ресей, Universitetskaya nab. 7-9, St. Petersburg, 199034
O. Glumov
St. Petersburg State University
Email: d.korolev@spbu.ru
Ресей, Universitetskaya nab. 7-9, St. Petersburg, 199034