Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III)
- Авторлар: Neklyudov V.1, Boos G.1, Chmutova G.1, Shulaeva M.2, Bagina Y.1, Amirov R.1
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Мекемелер:
- Kazan (Volga Region) Federal University, ul. Kremlevskaya 18
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Шығарылым: Том 88, № 8 (2018)
- Беттер: 1672-1680
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222369
- DOI: https://doi.org/10.1134/S1070363218080194
- ID: 222369
Дәйексөз келтіру
Аннотация
The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25°C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10–5 to 1.00 × 10–3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory.
Негізгі сөздер
Авторлар туралы
V. Neklyudov
Kazan (Volga Region) Federal University, ul. Kremlevskaya 18
Хат алмасуға жауапты Автор.
Email: VVNekljudov@kpfu.ru
Ресей, Kazan, Tatarstan, 420008
G. Boos
Kazan (Volga Region) Federal University, ul. Kremlevskaya 18
Email: VVNekljudov@kpfu.ru
Ресей, Kazan, Tatarstan, 420008
G. Chmutova
Kazan (Volga Region) Federal University, ul. Kremlevskaya 18
Email: VVNekljudov@kpfu.ru
Ресей, Kazan, Tatarstan, 420008
M. Shulaeva
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: VVNekljudov@kpfu.ru
Ресей, Kazan, Tatarstan, 420088
Yu. Bagina
Kazan (Volga Region) Federal University, ul. Kremlevskaya 18
Email: VVNekljudov@kpfu.ru
Ресей, Kazan, Tatarstan, 420008
R. Amirov
Kazan (Volga Region) Federal University, ul. Kremlevskaya 18
Email: VVNekljudov@kpfu.ru
Ресей, Kazan, Tatarstan, 420008
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