Dimerization of Pheophorbide а with Activated Carboxylic Group in the Reaction with Ethylenediamine
- Авторлар: Belykh D.1, Malshakova M.1
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Мекемелер:
- Institute of Chemistry, Komi Scientific Center, Ural Branch
- Шығарылым: Том 88, № 6 (2018)
- Беттер: 1133-1137
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222242
- DOI: https://doi.org/10.1134/S1070363218060142
- ID: 222242
Дәйексөз келтіру
Аннотация
The interaction of ethylenediamine with pheophorbide a, carboxylic group of the latter being activated with di-tert-butyl dicarbonate, has been studied. Acylation of two amino groups of ethylenediamine with activated pheophorbide a and the formation of phorbine-phorbine dimer with the macrocycles bound in the dimer via amide bonding with ethylenediamine bridge have been demonstrated. It has also be found that the phorbine-phorbine dimer is formed even in large excess of ethylenediamine with respect to pheophorbide a.
Негізгі сөздер
Авторлар туралы
D. Belykh
Institute of Chemistry, Komi Scientific Center, Ural Branch
Хат алмасуға жауапты Автор.
Email: belykh-dv@mail.ru
Ресей, ul. Pervomaiskaya 48, Syktyvkar, 167982
M. Malshakova
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: belykh-dv@mail.ru
Ресей, ul. Pervomaiskaya 48, Syktyvkar, 167982