Solubility of salts of  d -elements in organic and water-organic solvents: V. Inner-sphere chalcogen S–S contacts in the [Ni(DMSO) 4 (H 2 O) 2 ]Cl 2  solvate

N. A. Bogachev; N. A. Tsyrulnikov; G. L. Starova; M. Yu. Skripkin; A. B. Nikolskii

doi:10.1134/S1070363217110378

Solubility of salts of d-elements in organic and water-organic solvents: V. Inner-sphere chalcogen S–S contacts in the [Ni(DMSO)₄(H₂O)₂]Cl₂ solvate

Авторлар: Bogachev N.¹, Tsyrulnikov N.¹, Starova G.¹, Skripkin M.¹, Nikolskii A.¹
Мекемелер:
1. St. Petersburg State University
Шығарылым: Том 87, № 11 (2017)
Беттер: 2748-2749
Бөлім: Letters to the Editor
URL: https://journals.rcsi.science/1070-3632/article/view/221663
DOI: https://doi.org/10.1134/S1070363217110378
ID: 221663

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Статистика

Аннотация

It was proved by the IR spectroscopy that the first coordination sphere of nickel cations in the NiCl₂·2DMSO·9H₂O, NiCl₂·5DMSO·4H₂O, and NiCl₂·4DMSO·2H₂O compounds contains dimethyl sulfoxide and water ligands. According to X-ray structural analysis, in crystals of the NiCl₂·4DMSO·2H₂O compound, noncovalent contacts between sulfur atoms of neighboring dimethyl sulfoxide molecules are realized in the inner sphere of the complex.