Volatility of some aromatic nitrosubstituted plasticizers for polymers
- Авторлар: Golubev A.1, Novikov I.2, Kuvshinova S.2, Burmistrov V.2, Koifman O.2,3
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Мекемелер:
- Research Institute of Polymer Materials
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- Шығарылым: Том 87, № 9 (2017)
- Беттер: 2188-2194
- Бөлім: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
- URL: https://journals.rcsi.science/1070-3632/article/view/221354
- DOI: https://doi.org/10.1134/S1070363217090456
- ID: 221354
Дәйексөз келтіру
Аннотация
Nine derivatives of nitrophthalic acids and nitrophenols were synthesized as potential plasticizers for polymers and structurally characterized by 1H NMR and elemental analysis. The time dependences of the weight loss for the nitro derivatives synthesized and for commercial plasticizers (dibutyl phthalate and dioctyl phthalate) were obtained by gravimetric method at 100ºC, and their volatilities and dipole moments were calculated. The resultant nitroplasticizers are considerably less volatile than dibutyl phthalate. Low volatility is associated not so much with high molecular weight as with high polarity. The nitroplasticizers are well compatible with cellulose esters and exhibit low rates of migration from polymer films.
Негізгі сөздер
Авторлар туралы
A. Golubev
Research Institute of Polymer Materials
Хат алмасуға жауапты Автор.
Email: niipm@perm.ru
Ресей, ul. Chistopol’skaya 16, Perm, 614101
I. Novikov
Ivanovo State University of Chemistry and Technology
Email: niipm@perm.ru
Ресей, Sheremetevskii pr. 7, Ivanovo, 153000
S. Kuvshinova
Ivanovo State University of Chemistry and Technology
Email: niipm@perm.ru
Ресей, Sheremetevskii pr. 7, Ivanovo, 153000
V. Burmistrov
Ivanovo State University of Chemistry and Technology
Email: niipm@perm.ru
Ресей, Sheremetevskii pr. 7, Ivanovo, 153000
O. Koifman
Ivanovo State University of Chemistry and Technology; Krestov Institute of Solution Chemistry
Email: niipm@perm.ru
Ресей, Sheremetevskii pr. 7, Ivanovo, 153000; ul. Akademicheskaya 1, Ivanovo, 153045