New Tetrazole Tripodal Ligand Based on Triphenylphosphine Oxide

O. V. Bykhovskaya; A. G. Matveeva; M. P. Pasechnik; A. V. Vologzhanina; S. V. Matveev; I. Yu. Kudryavtsev; T. V. Baulina; V. K. Brel

doi:10.1134/S1070363219120120

New Tetrazole Tripodal Ligand Based on Triphenylphosphine Oxide

Authors: Bykhovskaya O.V.¹, Matveeva A.G.¹, Pasechnik M.P.¹, Vologzhanina A.V.¹, Matveev S.V.¹, Kudryavtsev I.Y.¹, Baulina T.V.¹, Brel V.K.¹
Affiliations:
1. Nesmeyanov Institute of Organoelement Compounds
Issue: Vol 89, No 12 (2019)
Pages: 2400-2407
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/223197
DOI: https://doi.org/10.1134/S1070363219120120
ID: 223197

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Abstract

A new tetrazole tripodal ligand, tris[2-(tetrazol-5-ylmethoxy)phenyl]phosphine oxide, has been obtained. Its structure in crystal and solutions has been elucidated by X-ray diffraction analysis as well as IR, Raman, and multinuclear (¹H, ¹³C, ³¹P) NMR spectroscopy. Coordination properties of the polydentate ligand have been studied as exemplified by the complexation with lanthanum(III).