Synthesis, Structure, and Luminescence Properties of Boron Complex with 4-Bromo-2-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenoxide Ligand
- Authors: Rozhkov A.V.1, Novikov A.S.1
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Affiliations:
- St. Petersburg State University
- Issue: Vol 89, No 11 (2019)
- Pages: 2246-2250
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223162
- DOI: https://doi.org/10.1134/S1070363219110148
- ID: 223162
Cite item
Abstract
A boron complex with 4-bromo-2-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenoxide ligand has been synthesized, and its photoluminescence properties in solution and in the solid phase have been examined. The structure of the complex has been determined by X-ray analysis. Non-classical intermolecular interaction (halogen bond) between the bromine and fluorine atoms has been detected in the crystal structure of the complex.
Keywords
About the authors
A. V. Rozhkov
St. Petersburg State University
Author for correspondence.
Email: iomcrozhkov@gmail.com
Russian Federation, St. Petersburg, 199034
A. S. Novikov
St. Petersburg State University
Email: iomcrozhkov@gmail.com
Russian Federation, St. Petersburg, 199034