Some Features of Reaction of 2-Methyl-1,4-naphthoquinone with H-Phosphonium Salts Based on Diphenylphosphine
- Authors: Khasiyatullina N.R.1, Islamov D.R.1, Mironov V.F.1
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Affiliations:
- A.E. Arbuzov Institute of Organic and Physical Chemistry
- Issue: Vol 89, No 11 (2019)
- Pages: 2219-2223
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223155
- DOI: https://doi.org/10.1134/S1070363219110094
- ID: 223155
Cite item
Abstract
It was shown that the direction of the reaction of 2-methyl-1,4-naphthoquinone with H-phosphonium salts obtained from diphenylphosphine and trifluoromethanesulfonic or trifluoroacetic acids depends on the nature of the anion. Structure of the obtained mono- and diphosphinates, as well as the quasi-phosphonium salt, was established by NMR spectroscopy and single crystal X-ray diffraction methods.
About the authors
N. R. Khasiyatullina
A.E. Arbuzov Institute of Organic and Physical Chemistry
Author for correspondence.
Email: nadya.ksu@mail.ru
Russian Federation, Kazan, 420088
D. R. Islamov
A.E. Arbuzov Institute of Organic and Physical Chemistry
Email: nadya.ksu@mail.ru
Russian Federation, Kazan, 420088
V. F. Mironov
A.E. Arbuzov Institute of Organic and Physical Chemistry
Email: nadya.ksu@mail.ru
Russian Federation, Kazan, 420088