Elucidation of the Structure of Products of Triphenylphosphine Electrooxidation in the Presence of Camphene
- Authors: Zagumennov V.A.1, Sizova N.A.1, Khayarov K.R.1, Litvinov I.A.2,3, Karamov F.A.3
-
Affiliations:
- Kazan (Volga Region) Federal University
- A.E. Arbuzov Institute of Organic and Physical Chemistry
- A.N. Tupolev Kazan National Research Technical University (KAI)
- Issue: Vol 89, No 9 (2019)
- Pages: 1777-1782
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223067
- DOI: https://doi.org/10.1134/S1070363219090081
- ID: 223067
Cite item
Abstract
The structure of the products of anodic oxidation of triphenylphosphine in the presence of camphene carried out in acetonitrile with sodium perchlorate as supporting electrolyte has been studied. The major product, triphenylphosphine oxide, has been isolated from the solution in the form of cocrystals of free triphenylphosphine oxide and its complex with sodium perchlorate. The molecular structure of the cocrystals has been studied by X-ray diffraction analysis. Triphenylcamphenylphosphonium perchlorate, bornylacetamide, and a terpene compound with triphenylphosphonium and acetamide substituents in the cycle have been detected by NMR 13C as the electrolysis side products.
About the authors
V. A. Zagumennov
Kazan (Volga Region) Federal University
Author for correspondence.
Email: vzagumen@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
N. A. Sizova
Kazan (Volga Region) Federal University
Email: vzagumen@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
Kh. R. Khayarov
Kazan (Volga Region) Federal University
Email: vzagumen@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
I. A. Litvinov
A.E. Arbuzov Institute of Organic and Physical Chemistry; A.N. Tupolev Kazan National Research Technical University (KAI)
Email: vzagumen@kpfu.ru
Russian Federation, Kazan, Tatarstan; Kazan, Tatarstan
F. A. Karamov
A.N. Tupolev Kazan National Research Technical University (KAI)
Email: vzagumen@kpfu.ru
Russian Federation, Kazan, Tatarstan