Synthesis, Structure, and Spectral Properties of 3,5-Di-tert-butyl-1,2-benzoquinone 3-Hydroxynaphthoyl Hydrazone and Its Complexes with Zn(II), Cd(II), Ni(II), and Co(II)


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Abstract

Novel complexes of Zn(II), Cd(II), Ni(II), and Co(II) with 3,5-di-tert-butyl-1,2-benzoquinone 3-hyd-roxynaphthoyl hydrazone have been synthesized. Composition, structure, magnetic and spectral properties of the obtained compounds have been studied by means of elemental analysis, IR, 1H NMR, and UV spectroscopy, X-ray diffraction analysis, quantum-chemical simulations, and magnetochemistry.

About the authors

A. S. Burlov

Research Institute of Physical and Organic Chemistry

Author for correspondence.
Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

S. B. Zaichenko

Research Institute of Physical and Organic Chemistry

Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

L. D. Popov

Southern Federal University

Email: anatoly.burlov@yandex.ru
Russian Federation, Rostov-on-Don

V. G. Vlasenko

Research Institute of Physics

Email: anatoly.burlov@yandex.ru
Russian Federation, Rostov-on-Don

G. S. Borodkin

Research Institute of Physical and Organic Chemistry

Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

N. I. Makarova

Research Institute of Physical and Organic Chemistry

Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

I. S. Vasilchenko

Research Institute of Physical and Organic Chemistry

Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

E. V. Korshunova

Research Institute of Physical and Organic Chemistry

Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

K. A. Lysenko

N.A. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Email: anatoly.burlov@yandex.ru
Russian Federation, Moscow

S. I. Levchenkov

Southern Federal University; Southern Scientific Center of the Russian Academy of Sciences

Email: anatoly.burlov@yandex.ru
Russian Federation, Rostov-on-Don; Rostov-on-Don

I. N. Shcherbakov

Southern Federal University

Email: anatoly.burlov@yandex.ru
Russian Federation, Rostov-on-Don


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