Synthesis of 8-Methyl-5-[(methylsulfanyl)methyl]-3-thiabicyclo[3.3.1]non-7-en-6-one and Its Extraction Ability for Gold(III)
- Authors: Golubyatnikova L.G.1, Khisamutdinov R.A.1, Baeva L.A.1, Murinov Y.I.1
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Affiliations:
- Ufa Institute of Chemistry
- Issue: Vol 88, No 12 (2018)
- Pages: 2524-2527
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222585
- DOI: https://doi.org/10.1134/S1070363218120113
- ID: 222585
Cite item
Abstract
An efficient one-pot procedure has been proposed for the synthesis of 8-methyl-5-[(methylsulfanyl) methyl]-3-thiabicyclo[3.3.1]non-7-en-6-one from accessible natural raw materials. A stable complex of the title compound with gold(III) has been obtained by the extraction method, and the mode of its coordination to the metal ion has been determined by IR and NMR spectroscopy.
About the authors
L. G. Golubyatnikova
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054
R. A. Khisamutdinov
Ufa Institute of Chemistry
Author for correspondence.
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054
L. A. Baeva
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054
Yu. I. Murinov
Ufa Institute of Chemistry
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054