Synthesis and Properties of Cobalt(II) Tetrakis-[4,5-di(4′-carboxy)phenylene(oxy/sulfanyl/amino)]phthalocyanines

A. P. Morozova; S. A. Znoiko; A. S. Vashurin; A. V. Zav’yalov; V. E. Maizlish; G. P. Shaposhnikov

doi:10.1134/S1070363218090451

Synthesis and Properties of Cobalt(II) Tetrakis-[4,5-di(4′-carboxy)phenylene(oxy/sulfanyl/amino)]phthalocyanines

Authors: Morozova A.P.¹, Znoiko S.A.¹, Vashurin A.S.¹, Zav’yalov A.V.¹, Maizlish V.E.¹, Shaposhnikov G.P.¹
Affiliations:
1. Research Institute of Macroheterocycles
Issue: Vol 88, No 9 (2018)
Pages: 2020-2027
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222459
DOI: https://doi.org/10.1134/S1070363218090451
ID: 222459

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Abstract

Phthalonitriles with fragments of 4-hydroxy, 4-mercapto and 4-aminobenzoic acids were synthesized by nucleophilic substitution in 4-bromo-5-nitrophthalonitrile. The synthesized phthalonitriles were used to prepare octasubstituted cobalt phthalocyanines by template synthesis. The spectral properties of the products were studied.