The Kabachnik–Fields Reaction in the Synthesis of Polyaminophosphonate Derivatives of p-tert-Butylthiacalix[4]arene
- Authors: Shibaeva K.S.1, Mostovaya O.A.1, Nazarova A.A.1, Shurpik D.N.1, Shiabiev I.E.1, Kuznetsova D.I.1, Stoykov I.I.1
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Affiliations:
- Butlerov Chemistry Institute
- Issue: Vol 88, No 9 (2018)
- Pages: 1812-1817
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222405
- DOI: https://doi.org/10.1134/S1070363218090086
- ID: 222405
Cite item
Abstract
Novel derivatives of p-tert-butylthiacalix[4]arene containing four or eight 1-aminophosphonate groups at the lower rim of the macrocycle in 1,3-alternate conformation have been synthesized via the Kabachnik–Fields reaction. These compounds are promising synthetic receptors for biologically important acids. It has been shown that complete phosphorylation of the first generation dendrimer containing eight primary amino groups is impeded in the case of cyclic ketones.
About the authors
K. S. Shibaeva
Butlerov Chemistry Institute
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
O. A. Mostovaya
Butlerov Chemistry Institute
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
A. A. Nazarova
Butlerov Chemistry Institute
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
D. N. Shurpik
Butlerov Chemistry Institute
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
I. E. Shiabiev
Butlerov Chemistry Institute
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
D. I. Kuznetsova
Butlerov Chemistry Institute
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
I. I. Stoykov
Butlerov Chemistry Institute
Author for correspondence.
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008