Synthesis and Estimation of Radical Scavenging Activity of Tetra(meso-aryl)porphyrins Containing 2,6-Dimethoxyphenol Unit
- Authors: Rocheva T.K.1, Mazaletskaya L.I.2, Sheludchenko N.I.2, Belykh D.V.1
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Affiliations:
- Institute of Chemistry, Komi Scientific Center, Ural Branch
- Emanuel Institute of Biochemical Physics
- Issue: Vol 88, No 8 (2018)
- Pages: 1635-1640
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222363
- DOI: https://doi.org/10.1134/S1070363218080145
- ID: 222363
Cite item
Abstract
Tetra(meso-aryl)porphyrins containing 2,6-dimethoxyphenol unit distant from the macrocycle and adjacent to it have been prepared. Radical scavenging activity of the obtained compounds has been estimated in the model reaction of ethylbenzene oxidation initiated by azobisisobutyronitrile. It has been shown that the phenol hydroxy group ability to inhibit ethylbenzene oxidation depends on the environment of phenol group.
About the authors
T. K. Rocheva
Institute of Chemistry, Komi Scientific Center, Ural Branch
Author for correspondence.
Email: tatyanrocheva@yandex.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167000
L. I. Mazaletskaya
Emanuel Institute of Biochemical Physics
Email: tatyanrocheva@yandex.ru
Russian Federation, Moscow
N. I. Sheludchenko
Emanuel Institute of Biochemical Physics
Email: tatyanrocheva@yandex.ru
Russian Federation, Moscow
D. V. Belykh
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: tatyanrocheva@yandex.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167000