Email this article Reaction of Zirconium Tetrachloride with 2,2-Dimethylbutanoic Acid
- Authors: Makhaev B.D.1, Petrova L.A.1
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Affiliations:
- Institute of Problems of Chemical Physics
- Issue: Vol 88, No 7 (2018)
- Pages: 1430-1435
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222316
- DOI: https://doi.org/10.1134/S1070363218070137
- ID: 222316
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Abstract
The reaction of ZrCl4 with 2,2-dimethylbutanoic acid in excess of the acid and also in o-xylene at boiling point of the solvent was studied. Formed zirconium tetrakis(2,2-dimethylbutanoate) is volatile in vacuum that allows its using as a precursor for the preparation of inorganic materials by chemical vapor deposition. During the reaction Zr(C6H11O2)4 is condensed to form polynuclear complexes.
About the authors
B. D. Makhaev
Institute of Problems of Chemical Physics
Author for correspondence.
Email: vim@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, 142432
L. A. Petrova
Institute of Problems of Chemical Physics
Email: vim@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, 142432
